Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific     

Yoshihisa?MinoEmail author  Chiho?Sukigara  Makio?C.?Honda  Hajime?Kawakami  Kazuhiko?Matsumoto  Masahide?Wakita  Minoru?Kitamura  Tetsuichi?Fujiki  Kosei?Sasaoka  Osamu?Abe  Jan?Kaiser  Toshiro?Saino 《Journal of Oceanography》2016,72(6):819-836

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.  相似文献   

Hypocenter distribution and focal mechanism of AE events during two stress stage creep in Yugawara andesite     

Osamu Nishizawa  Kaoru Onai  Kinichro Kusunose 《Pure and Applied Geophysics》1984,122(1):36-52

More than a thousand acoustic-emission (AE) hypocenters were determined in a cylindrical andesite specimen under two-stage uniaxial creep at stresses of 204 and 214 MPa. Strains were monitored for 6 peripheral points at the middle part of the cylindrical specimen's wall. The strain data indicate gradual increase of nonuniform deformation during steady creep and strong intensification of the nonuniformity during acceleration creep and, therefore, biased stress distribution within the specimen. The correlation between dilatant strain and AE hypocenters was investigated for whether or not tensile cracks emit AE. The region with high AE activity shows only a small dilatant strain. This negative correlation between AE and the dilatant region may eliminate tensile cracks as possible AE sources. A composite focal-mechanism solution of local AE events, covering a wide solid angle of the focal hemisphere, indicates that shear fractures emit AE waves. The direction of the compressional axis in this solution shows a significant deviation from that inferred from the applied external force, suggesting that the local stress field is governed by preexisting weak zones that are, presumably, produced by tensile cracks within the specimen. AE hypocenters tended to form clusters during steady creep under the constant compressional stress. During acceleration creep caused by a small step increase of the external stress, the preceding clusters disappeared while a new cluster appeared in an incipient fault plane. This suggests that changes in seismicity pattern such as migrations or quiescences of swarm—important clues for earthquake predictions—may be caused by an instantaneous change in the tectonic-stress levels.  相似文献   

Antiferromagnetic transition of fayalite under high pressure studied by Mössbauer spectroscopy     

Mitsuhiko Hayashi  Ichiro Tamura  Osamu Shimomura  Hiroshi Sawamoto  Haruki Kawamura 《Physics and Chemistry of Minerals》1987,14(4):341-344

Néel temperature (Tm _N of α-Fe₂SiO₄ (fayalite) was measured as a function of pressure by means of Mössbauer spectroscopy in the pressure range 0–16 Gpa. High pressure was generated using a clamp-type miniature diamond anvil cell which was inserted into a cryostat. The Néel temperature increased linearly with increasing pressure at a rate of dT _N /dp=2.2±0.2 K/GPa. The result is discussed on the basis of the model proposed for the magnetic structure of fayalite by Santoro et al. (1966). The observed dT _N /dp suggests that the superexchange interactions vary as the ?10/3 power of the volume while the volume dependence of the direct exchange interactions is positive and small.  相似文献   

Microprobe mineralogy of plagioclase, clinopyroxene and amphibole as records of cooling rate in the Shirotori—Hiketa dike swarm, northeastern Shikoku, Japan     

Osamu Ujike 《Lithos》1982,15(4):281-287

A compositional gap between hypersolidus plagioclase and subsolidus plagioclase, most of which must have formed by devitrification, decreases in An % with decreasing cooling rate, probably reflecting a melt composition derived by in situ differentiation. Augitic pyroxenes, crystallized from a quickly cooling magma, tend to contain more Al, Ti, Na(+K) and Fe³⁺, and less Si and Mn. Compositional breaks between hypersolidus and subsolidus amphiboles with respect to the components of edenite and titanoamphibole, decrease in width with decreasing cooling rate. Subcalcic hornblende seems to grow from differentiated magmas in the course of moderate to rapid cooling.  相似文献   

Overview of Holocene Tsunami Deposits along the Nankai,Suruga, and Sagami Troughs,Southwest Japan     

Junko Komatsubara  Osamu Fujiwara 《Pure and Applied Geophysics》2007,164(2-3):493-507

Tsunami deposits provide a basis for reconstructing Holocene histories of great earthquakes and tsunamis on the Pacific Coast of southwest Japan. The deposits have been found in the past 15 years at lakes, lagoons, outcrops, and archaeological excavations. The inferred tsunami histories span 3000 years for the Nankai and Suruga Troughs and nearly 10,000 years for the Sagami Trough. The inferred histories contain recurrence intervals of variable length. The shortest of these —100–200 years for the Nankai Trough, 150–300 years for the Sagami Trough — resemble those known from written history of the past 1000–1500 years. Longer intervals inferred from the tsunami deposits probably reflect variability in rupture mode, incompleteness of geologic records, and insufficient research. The region's tsunami history could be clarified by improving the geologic distinction between tsunami and storm, dating the inferred tsunamis more accurately and precisely, and using the deposits to help quantify the source areas and sizes of the parent earthquakes.  相似文献   

日本南海海槽天然气水合物研究现状   总被引：8，自引：3，他引：8  

宋海斌  松林修 《地球物理学进展》2001,16(2):88-98

本文介绍日本在其周围海域特别是南海海槽的海洋天然气水合物研究工作，首先介绍其研究简史，研究计划，研究队伍及早期研究成果，其次，介绍了西南海海槽天然气水合物的勘探、研究状况，然后,介绍了五年计划实施的东南海海槽地球物理勘探、钻探状况，最后指出，南海海槽的一些新资料深入的综合研究无疑会给世界水合物研究增添新的内容。  相似文献   

Oxygen and Carbon Isotope Study of Calcite and Dolomite in the Disseminated Au-Ag Telluride Bulawan Deposit, Negros Island, Philippines     

Victor B. MAGLAMBAYAN  Daizo ISHIYAMA  Toshio MIZUTA  Osamu MATSUBAYA  Yohei ISHIKAWA 《Resource Geology》2001,51(2):107-116

Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ¹⁸O and δ¹³C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ¹⁸O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ¹³C values range from ‐6.1 to ‐1.0%. The δ¹⁸O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ¹³C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ¹⁸O and δ¹³C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ¹⁸O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ¹⁸O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and ¹⁸O‐enriched fluids which reacted with ¹⁸O‐ and ¹³C‐rich wallrocks such as limestone.  相似文献   

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene     

Richard Winterhalter  Peter Neeb  Dirk Grossmann  Antje Kolloff  Osamu Horie  Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献   

Identification of tsunami deposits considering the tsunami waveform: An example of subaqueous tsunami deposits in Holocene shallow bay on southern Boso Peninsula, Central Japan     

Osamu Fujiwara  Takanobu Kamataki   《Sedimentary Geology》2007,200(3-4):295-313

This study proposes a tsunami depositional model based on observations of emerged Holocene tsunami deposits in outcrops located in eastern Japan. The model is also applicable to the identification of other deposits, such as those laid down by storms. The tsunami deposits described were formed in a small bay of 10–20-m water depth, and are mainly composed of sand and gravel. They show various sedimentary structures, including hummocky cross-stratification (HCS) and inverse and normal grading. Although, individually, the sedimentary structures are similar to those commonly found in storm deposits, the combination of vertical stacking in the tsunami deposits makes a unique pattern. This vertical stacking of internal structures is due to the waveform of the source tsunamis, reflecting: 1) extremely long wavelengths and wave period, and 2) temporal changes of wave sizes from the beginning to end of the tsunamis.

The tsunami deposits display many sub-layers with scoured and graded structures. Each sub-layer, especially in sandy facies, is characterized by HCS and inverse and normal grading that are the result of deposition from prolonged high-energy sediment flows. The vertical stack of sub-layers shows incremental deposition from the repeated sediment flows. Mud drapes cover the sub-layers and indicate the existence of flow-velocity stagnant stages between each sediment flow. Current reversals within the sub-layers indicate the repeated occurrence of the up- and return-flows.

The tsunami deposits are vertically divided into four depositional units, Tna to Tnd in ascending order, reflecting the temporal change of wave sizes in the tsunami wave trains. Unit Tna is relatively fine-grained and indicative of small tsunami waves during the early stage of the tsunami. Unit Tnb is a protruding coarse-grained and thickest-stratified division and is the result of a relatively large wave group during the middle stage of the tsunami. Unit Tnc is a fine alternation of thin sand sheets and mud drapes, deposited from waning waves during the later stage of the tsunami. Unit Tnd is deposited during the final stage of the tsunami and is composed mainly of suspension fallout. Cyclic build up of these sub-layers and depositional units cannot be explained by storm waves with short wave periods of several to ten seconds common in small bays.  相似文献   

Isotopic anomalies of rare gases in the Nigorikawa geothermal area,Hokkaido, Japan     

Keisuke Nagao  Nobuo Takaoka  Osamu Matsubayashi 《Earth and Planetary Science Letters》1979,44(1):82-90

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